1.
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Which of the following processes are spontaneous? a. H3O+(aq) + Cl-(aq) ---> HCl(aq) + H2O(l) b. CH4(g) + 2 O2(g) ---> CO2(g) + 2 H2O(g) c. NaCl(s) + H2O(l) ---> Na+(aq, 1M) + Cl- (aq, 1 M) d. AgCl(s) + H2O(l) ---> Ag+(aq, 1 M) + Cl-(aq, 1 M)
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2.
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For which of the following is G > 0? a. HC2H3O2(aq) + H2O(l) <==> H3O+(aq) + C2H3O2-(aq) b. Br2(l) ---> Br2(s) at 25°C c. 2 Na(s) + Cl2(g) ---> 2 NaCl(s)
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3.
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Hfusion of ethanol is 5.01 kJ/mol, and its melting point is -114°C. What is S for s ---> l at the melting point?
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4.
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Use thermodynamic data in the appendix of your text to determine G° for the process below at 298 K. 4 NH3(g) + 5 O2(g) ---> 4 NO(g) + 6 H2O(g)
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5.
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For 2 NaHCO3(s) <==> Na2CO3(s) + CO2(g) + H2O(g), Kp = 0.23 at 100°C. What is G° at this temperature?
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6.
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Find Keq for the process CH3CH2OH(l) ---> C2H4(g)+ H2O(l) at 298 K.
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7.
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Find Keq at 500 K for CO(g) + 2 H2(g) <==> CH3OH(g).
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8.
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The reaction below is nonspontaneous at 25°C. Which of the following reactions could be coupled with this reaction to make the production of iron spontaneous? 2 Fe2O3(s) ---> 4 Fe(s) + 3 O2(g)
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9.
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"In a spontaneous process the entropy of the universe increases" is a statement of the
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10.
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Consider the reaction: N2O4(g) <==> 2 NO2(g) Keq = 0.1134 at 20°C, and the change in enthalpy of the reaction is 58.03 kJ/mol. What is Keq for this reaction at 400 K?
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